17-Jul-2014, MF Hg(Ar) & Ar Oriel pen lamps From the Oriel Spectral Calibration Lamps booklet: "The Hg(Ar) and Hg-Ne lamps contain a small amount of mercury which dominates the output spectrum, and argon or neon as a starter gas. The spectral output of the 6035 Hg(Ar) lamps is effectively that of the mercury lines." SAFETY CONSIDERATIONS: "Although low power, these lamps emit intense UV, ... wear UV protective eyewear and gloves when operating them." The other Oriel pen lamps are "rare gas" lamps: Ar, Ne, Kr, Xe Hg has a one BIG UV emission at 253.7 nm, and less intense but big lines at 296.7, 312.6 nm. From the NIST Atomic Spectra Database Observed Wavelength Air (nm), Relative Intensity Hg I 253.6521 15,000 Hg I 296.7283 1,200 Hg I 312.5674 400 Hg I 313.155 320 Hg I 314.1844 320 Note: These UV lines are below the spectral range of MOS2, however, Lu MOS sees second order (2X wavelength) of these - via a Spectralon integrating sphere - MOBY Lu does not see these. 253.6521 * 2 = 507.3042 nm = BIG 296.7283 * 2 = 593.4566 nm = @ left shoulder of Reflection Peak 312.5674 * 2 = 625.1348 nm = BIG 313.155 * 2 = 626.31 nm 314.1844 * 2 = 628.3688 nm Maybe these second order lines could be used for wavelength calibration? Or, are they also doubled in line width? Since our Ekspla NT242 laser's lowest wavelength is 300 nm, on 15-Jul-2014, via MOS204cfg15 Lu & Spectralon sphere I scanned 300 nm Ekspla output, seen by Lu MOS BSG at 600 nm 312.55, 313.15, 313.20 nm, seen by MOS ~ 626 nm, 317.50 nm, seen by MOS at end of BSG at 635 nm. For MOS/MOBY wavelength calibrations I have scanned Hg(Ar) pen lamp - assuming it's output contained both Hg and Ar lines. I did not scan the Ar lamp. From the NIST ASD I used listings for lines of Hg and Ar to retrieve wavelengths for the Hg(Ar) scans. On 16-Jul-2014, via MOS204cfg15 Lu & Spectralon sphere I scanned our Ar Oriel pen lamp. There are two lines in the Hg spectrum 404.6565 & 546.0750 nm, which should not be used from the Hg(Ar) lamp for BSG calibration because they are really doubles from the Ar spectrun at 404.4418 & 545.1652 nm. There are several RSG lines from the Hg(Ar) lamp which I have been using for wavelength calibrations which are from the Ar spectrum, and are really multiple-lines, and should not have been used: I've used 675.28 nm, which is a triple line from 675.2834, 675.6163, 676.6612 nm 706.67 is a double: 706.7218, 706.8736 (maybe the ".67" was a typo?) 714.7 is a double: 714.7042, 715.8839 727.29 is a triple: 726.5172, 727.0664, 727.2936 738.4 is a triple: 737.2118, 738.3980, 739.2980 The Ar lamp has 17 BSG lines which to not appear in the output of the Hg(Ar) lamp (which will be especially useful for nUV wavelength calibration): 355.4306, 360.6522, 383.4679, 430.0101, 459.6097, 462.8441, 518.7746, 522.1271, 542.1352, 545.1652, 560.6733, 565.0704, 573.9520, 583.4263, 586.0310, 591.2085, 614.5441 nm. Note: the Ar 404.4418 line causes the Hg 404.6565 to be a double in the Hg(Ar) output, but the Ar 404.4418 is a single in the Ar output. Ditto the Ar 545.1652 and Hg 546.0750 lines. Maybe I will use only the Hg I NIST lines from Hg(Ar) lamp, and use Ar I NIST lines from the Ar lamp - i.e. drop the RSG Ar lines from the Hg(Ar) useful set ?